Otsuka, Shinya’s team published research in Heteroatom Chemistry in 29 | CAS: 1375325-77-1

Heteroatom Chemistry published new progress about 1375325-77-1. 1375325-77-1 belongs to chlorides-buliding-blocks, auxiliary class Palladium, name is Chloro[(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2-amino-1,1-biphenyl)]palladium(ii), and the molecular formula is C51H42ClNOP2Pd, COA of Formula: C51H42ClNOP2Pd.

Otsuka, Shinya published the artcileSynthesis of 4-aryl- and 4-acyl-1,3-dithiole-2-thiones via deprotonative zincation of 1,3-dithiole-2-thione, COA of Formula: C51H42ClNOP2Pd, the publication is Heteroatom Chemistry (2018), 29(3), n/a, database is CAplus.

Deprotonative zincation of 1,3-dithiole-2-thione at the 4-position was developed. Addition of lithium diisopropylamide to a THF solution of 1,3-dithiole-2-thione containing ZnI2 and LiI generated the corresponding organozinc species. After this zincation, various aryl and acyl groups were installed at the 4-position by Pd-catalyzed cross-coupling reaction with aryl iodides and Cu-catalyzed acylation with acyl chlorides, resp.

Heteroatom Chemistry published new progress about 1375325-77-1. 1375325-77-1 belongs to chlorides-buliding-blocks, auxiliary class Palladium, name is Chloro[(4,5-bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2-amino-1,1-biphenyl)]palladium(ii), and the molecular formula is C51H42ClNOP2Pd, COA of Formula: C51H42ClNOP2Pd.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics