Wang, Guan-Wu published the artcileMechanochemical aminochlorination of electron-deficient olefins with chloramine-T promoted by (diacetoxyiodo)benzene, Name: Sodium chloro(tosyl)amide trihydrate, the publication is Advanced Synthesis & Catalysis (2007), 349(11+12), 1977-1982, database is CAplus.
A direct and convenient procedure for the solvent-free mechanochem. aminochlorination of electron-deficient olefins promoted by (diacetoxyiodo)benzene [PhI(OAc)2] was described using com. available and cheap chloramine-T as a nitrogen and chlorine source. The vicinal chloramine derivatives were obtained in high regio- and stereoselectivity with good yields. PhI(OAc)2 was superior to metal salts for the aminochlorination of electron-deficient olefins.
Advanced Synthesis & Catalysis published new progress about 7080-50-4. 7080-50-4 belongs to chlorides-buliding-blocks, auxiliary class Halogenation Reagent,Inhibitor, name is Sodium chloro(tosyl)amide trihydrate, and the molecular formula is C10H10O2, Name: Sodium chloro(tosyl)amide trihydrate.
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