Wu, Yu-Xi published the artcileCopper-Catalyzed Synthesis of O/N-Alkyl S-Phenyl Phenylcarbamothioates: An Odorless and Chemo-selective Chan-Lam Reaction to Construct C-S Bond, Name: 2-Chloro-4-methylphenylboronic acid, the publication is European Journal of Organic Chemistry (2022), 2022(32), e202200707, database is CAplus.
The O/N-alkyl-S-phenyl-(Z)-phenylcarbamothioates I [R1 = H, 4-Me, 4-Cl, etc.; R2 = OMe, OEt, OBu, N-morpholinyl; R3 = H, 3-Br, 4-Ph, etc.] were synthesized via copper-catalyzed chemoselective Chan-Lam reaction of odorless O/N-alkyl phenylthiocarbamates as sulfur sources and com. available phenylboronic acids as substrates. This methodol. featured simple performance, odorless sulfur source, easily available starting material, good functional group tolerance, and high chemo-selectivity to construct C-S bonds, thereby provided an alternative way to the synthesis of potentially bioactive compounds
European Journal of Organic Chemistry published new progress about 145349-62-8. 145349-62-8 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Boronic acid and ester,Benzene,Boronic Acids, name is 2-Chloro-4-methylphenylboronic acid, and the molecular formula is C7H3IN2O2, Name: 2-Chloro-4-methylphenylboronic acid.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics