Yearick, Kimberly published the artcileCatalytic Enantioselective Addition of Diethylzinc to Trifluoromethyl Ketones, Synthetic Route of 5860-95-7, the publication is Organic Letters (2008), 10(17), 3915-3918, database is CAplus and MEDLINE.
A procedure for nucleophilic addition of diethylzinc to trifluoromethyl ketones was developed. The TMEDA-catalyzed method converts aromatic substrates to the corresponding 2-aryl-1,1,1-trifluorobutan-2-ols in up to 99% yield, and it is also applicable to less reactive aliphatic ketones if stoichiometric ligand amounts are employed. The first asym. variant producing tertiary alcs. with up to 61% ee when TBOX is used as catalyst is described.
Organic Letters published new progress about 5860-95-7. 5860-95-7 belongs to chlorides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Chloride,Benzene,Ketone, name is 1-(2-Chlorophenyl)-2,2,2-trifluoroethanone, and the molecular formula is C9H12O, Synthetic Route of 5860-95-7.
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