Yearick, Kimberly published the artcileCatalytic enantioselective addition of diethylzinc to trifluoromethyl ketones. [Erratum to document cited in CA149:307341], Quality Control of 5860-95-7, the publication is Organic Letters (2008), 10(19), 4391, database is CAplus.
On page 3915, we overlooked previous work by Sasaki et. al. which discusses the enantioselective synthesis of tertiary alcs. via addition of diethylzinc to trifluoromethyl ketones in the presence of nitrogen-containing polydentate ligands. The following reference citation should be included: “Higashiyama, K.; Sasaki, S.; Kubo, H.; Yamauchi, T.; Ishii, A.; Kanai, M. Japanese Patent 200609692, Apr. 13, 2006.”.
Organic Letters published new progress about 5860-95-7. 5860-95-7 belongs to chlorides-buliding-blocks, auxiliary class Trifluoromethyl,Fluoride,Chloride,Benzene,Ketone, name is 1-(2-Chlorophenyl)-2,2,2-trifluoroethanone, and the molecular formula is C5H9IO2, Quality Control of 5860-95-7.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics