Frank, Arlen W.’s team published research in Journal of Organic Chemistry in 29 | CAS: 866-23-9

Journal of Organic Chemistry published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, COA of Formula: C5H10Cl3O3P.

Frank, Arlen W. published the artcileStability of the carbon-phosphorus bond in trichloromethyl- phosphonate esters. Ether formation in reactions with alcohols and phenols, COA of Formula: C5H10Cl3O3P, the publication is Journal of Organic Chemistry (1964), 29(12), 3706-7, database is CAplus.

Prolonged refluxing of a solution of Cl3CP(O)(OEt)2 (I) in alc. gave Et2O and Cl3CP(O)(OEt)OH. Thus, the ester behaved as an alkylating agent as in the reaction with amines. The reaction was remarkably mild. No alkylation was observed when di-Et ethylphosphonate or di-Et acetylphosphonate were refluxed with alc. under the same conditions. Alkylation of PhOH by I gave 85% phenetole in 4.5 hrs. at 150°.

Journal of Organic Chemistry published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, COA of Formula: C5H10Cl3O3P.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics