Gramstad, Thor’s team published research in Spectrochimica Acta in 19 | CAS: 866-23-9

Spectrochimica Acta published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, SDS of cas: 866-23-9.

Gramstad, Thor published the artcileHydrogen bonding. VII. Hydrogen-bond association of phenol and pentachlorophenol with carbonyl compounds and ethers, SDS of cas: 866-23-9, the publication is Spectrochimica Acta (1963), 497-508, database is CAplus.

cf. Acta Chem. Scand. 16, 2368(1962); CA 58, 1333b. The thermodn. data for the 1:1 association of PhOH with 8 esters, 3 acid fluorides, 16 ketones, 14 aldehydes, and 15 ethers in CCl4 solution were determined The frequency shifts, δvOH, of the O-H band of PhOH which accompanies the formation of the H bond with various types of proton acceptors (N,N-disubstituted amides, esters, ketones, aldehydes, ethers, and organo-P compounds) are proportional to the corresponding enthalpies of association This relation is not applicable to other proton donors studied. The entropy of association (-ΔS) for the various systems is, in relation to δvOH, in order of increasing values as follows: organo-P compounds-PhOH <N,N-disubstituted amides-PhOH < esters-PhOH < ketones-PhOH < aldehydes-PhOH < ethers-PhOH < tertiary amines and pyridines-PhOH. The influence of inductive and mesomeric effects on the H-bond association is discussed.

Spectrochimica Acta published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, SDS of cas: 866-23-9.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics