Griffin, C. E. published the artcileReaction of trichloromethyl radicals with triethyl phosphite, Category: chlorides-buliding-blocks, the publication is Chemistry & Industry (London, United Kingdom) (1958), 415, database is CAplus.
CCl4 and (EtO)3P at 80° give 80-5% Cl3CP(O)(OEt)2 (I). The reaction is inhibited by hydroquinone but traces of Bz2O2 give a 4-fold increase in reaction rate (89% yield at 80°). Irradiation of the reaction mixture at room temperature with a Hanovia ultraviolet lamp gives 80% I; under similar conditions BrCCl3 and (EtO)3P give 88% I. No reaction is observed in the dark at room temperature (30 days). These results confirm the chain process proposed by Kamai and Kharrasova (C.A. 52, 3666a). I b17 137-8°, n21D 1.4612; partial hydrolysis with PhNH2 in PhMe at 110° gave the anilinium salt of monoethyl trichloromethanephosphonate, m. 181.6-2.2° (MeOH-PhMe).
Chemistry & Industry (London, United Kingdom) published new progress about 866-23-9. 866-23-9 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Diethyltrichloromethylphosphonate, and the molecular formula is C5H10Cl3O3P, Category: chlorides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics