Li, Yang published the artcilePalladium-catalyzed Suzuki-Miyaura reaction of fluorinated vinyl chloride: a new approach for synthesis α and α,β-trifluoromethylstyrenes, Related Products of chlorides-buliding-blocks, the publication is Tetrahedron (2016), 72(37), 5684-5690, database is CAplus.
A mild and efficient palladium-catalyzed cross-coupling between fluorinated vinyl chloride and arylboronic acids was described. The use of ligand B successfully overcame the strong electronic withdrawing of trifluoromethylated substrates and allowed the efficient synthesis of a wide range of α and α,β-trifluoromethyl containing olefins. By using this method, the key intermediate for synthesis of Efavirenz was obtained in a simple route. The efficient conversion of two Freon mols. into useful α and α,α-trifluoromethyl containing olefins was a useful route in organic chem.
Tetrahedron published new progress about 532924-25-7. 532924-25-7 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Nitro Compound,Boronic acid and ester,Benzene,Boronic Acids,Boronic Acids,Boronic acid and ester,, name is (5-Chloro-2-nitrophenyl)boronic acid, and the molecular formula is C6H5BClNO4, Related Products of chlorides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics