Liu, Changchun published the artcileSynthesis and fungicidal activity of (2-chloropyridin-5-yl)methyl carbamates, Safety of 3-Chloro-4-fluoronitrobenzene, the publication is Nongyaoxue Xuebao (2015), 17(1), 97-100, database is CAplus.
Eleven novel (2-ehloropyridin-S-yl)methyl carbamates were synthesized by Pd-Fe/TiO2 catalyzed carbonylation of aromatic nitro-compounds and (2-chloropyridin-S-yl) methanol with carbon monoxide. Their structures were confirmed by 1H NMR and MS. Preliminary fungicidal activity tests indicated that some of the target compounds exhibited certain degree of inhibiting effect against four tested strains at the concentration of 50 mg/L. The inhibition rate against Gibberella zeae was over 77.3% for compound I [(2-chloropyridin-5-yl)methyl (4-methoxyphenyl) carbamate], II [(2-chloropyridin-5-yl)methyl (2,4-dichlorophenyl) carbamate] and III [(2-ehloropyridin-S-yl)methyl (3,4-dichlorophenyl) carbamate]. Compound I showed 82.5% of inhibition rate against Physalospora piricola, that was almost equal to carbendazim. All compounds showed better fungicidal activities against Botrytis cinerea than carbendazim.
Nongyaoxue Xuebao published new progress about 350-30-1. 350-30-1 belongs to chlorides-buliding-blocks, auxiliary class Fluoride,Chloride,Nitro Compound,Benzene, name is 3-Chloro-4-fluoronitrobenzene, and the molecular formula is C6H3ClFNO2, Safety of 3-Chloro-4-fluoronitrobenzene.
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https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics