Ohya, Kazumi published the artcilePyrolysis reaction of carpronium chloride and its structurally related compounds. 1. Electronic and steric effects on the orientation of the pyrolysis reaction, Application of 3-Carboxy-N,N,N-trimethylpropan-1-aminium chloride, the publication is Organic Mass Spectrometry (1983), 18(1), 27-33, database is CAplus.
The pyrolysis reaction of carpronium chloride [MeO2C(CH2)3N+Me3 Cl–] and the structurally related compounds RO2C(CH2)nN+Me3 Cl– (n = 2, 4, R = Me, Et, CHMe2; n = 3, R = H, Et, CHMe2), were studied by gas chromatog.-mass spectroscopy. The reaction modes of these ammonium compounds are dependent on the number of skeletal methylene groups and on the length of the carbon chain of the ester group. These phenomena were interpreted in terms of electronic and steric contributions for the ionic elimination reaction. The electronic and steric effects on the orientation of the reaction were discussed on the basis of the at. population calculated by the CNDO/2 method.
Organic Mass Spectrometry published new progress about 6249-56-5. 6249-56-5 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst,Inhibitor,Natural product, name is 3-Carboxy-N,N,N-trimethylpropan-1-aminium chloride, and the molecular formula is C7H16ClNO2, Application of 3-Carboxy-N,N,N-trimethylpropan-1-aminium chloride.
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