Baj, Stefan published the artcileTri-liquid system in the synthesis of dialkyl peroxides using tetraalkylammonium salts as phase-transfer catalysts, Name: N-Benzyl-N,N-dibutylbutan-1-aminium chloride, the publication is Applied Catalysis, A: General (2010), 385(1-2), 208-213, database is CAplus.
A highly effective method to synthesize dialkyl peroxides from alkyl hydroperoxides and alkyl bromides in a liquid-liquid-liquid system using tetraalkylammonium salts as phase-transfer catalysts is reported. This process was conducted in the presence of highly concentrated aqueous KOH solutions and cyclohexane as an organic solvent. In a liquid-liquid-liquid system, the phase-transfer catalyst forms an insoluble third-liquid phase between the organic and aqueous phases that enables the catalyst to be recycled multiple times. Dialkyl peroxides were obtained in high yields and with 100% selectivity.
Applied Catalysis, A: General published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, Name: N-Benzyl-N,N-dibutylbutan-1-aminium chloride.
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