Campagnol, Nicolo published the artcileOn the electrochemical deposition of metal-organic frameworks, Product Details of C6H4ClNO2, the publication is Journal of Materials Chemistry A: Materials for Energy and Sustainability (2016), 4(10), 3914-3925, database is CAplus.
The electrochem. deposition of Metal-Organic Frameworks (MOFs) is an interesting technique to synthesize adherent, microporous layers on top of conductive substrates. The technique can be subdivided in two approaches: anodic and cathodic deposition. While the mechanism of the cathodic approach has already been well studied, at least for MOF-5 not much is known about the anodic approach. A four-step mechanism is proposed to better understand the anodic deposition, and the same MOF used for the study, HKUST-1, is also deposited cathodically to compare the two approaches. This study focuses on how nucleation starts and proceeds, on the influence of the potential applied, the stresses in the growing layers, and the origin of defects like delamination and MOF detachment. The study is followed by critical considerations on the methods and on the technique, together with suggestions and guidelines to synthesize new MOF layers.
Journal of Materials Chemistry A: Materials for Energy and Sustainability published new progress about 6313-54-8. 6313-54-8 belongs to chlorides-buliding-blocks, auxiliary class Pyridine,Chloride,Carboxylic acid, name is 2-Chloroisonicotinic acid, and the molecular formula is C6H4ClNO2, Product Details of C6H4ClNO2.
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https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics