Ghosh, Biswajit published the artcileMolecular Interactions of Some Bioactive Molecules Prevalent in Aqueous Ionic Liquid Solutions at Different Temperatures Investigated by Experimental and Computational Contrivance, Category: chlorides-buliding-blocks, the publication is Fluid Phase Equilibria (2022), 113415, database is CAplus.
The solute -solvent interaction between ionic liquids (ILs) and amino acids (AA) in aqueous media plays a significant role for the optimization of a number of important biotechnol. processes. L-Valine and L-Proline (two solute mols.) interact with an ionic liquid (Benzyltributylammonium chloride) in aqueous medium. Based on the different parameters such as apparent molar volume, viscosity B-coefficient, molar refraction, molar conductance at different temperatures and different concentrations from d., viscosity, refractive index, conductance measurements have been used to explain the mol. level interactions which was supported by NMR and UV-Vis studies. Using Masson equation, the exptl. slopes and the limiting apparent molar volumes are obtained which explain the solute-solute and solute-solvent interactions. Hepler’s technique and dB/dT values have been used to examine the structure-making and structure-breaking nature of the solutes in the solvents. Viscosity parameters, A and B obtained from Jones-Doles equation explained the solute-solute and solute-solvent interactions in the solution Lorentz-Lorenz equation has used to calculate the molar refraction. The specific conductance also explained the interaction properties. Further the findings have been supported by NMR study of the solutions and also considerable amount of theor. anal. has been done which was in good agreement with the exptl. result. The behavior of many other bio-mols. can be explained by considering amino acids as model and the mechanism has been extended to elucidate the behavior of other (biol.) systems. In our findings we were emphasized on the nature of solute-solvent interactions and the presence of structural effect on the solvent in solution to analyze the mol.-level interactions prevalent in the systems.
Fluid Phase Equilibria published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, Category: chlorides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics