Kim, Hun Young published the artcileReversal of Enantioselectivity Approach to BINOLs via Single and Dual 2-Naphthol Activation Modes, Quality Control of 21286-54-4, the publication is Organic Letters (2017), 19(14), 3867-3870, database is CAplus and MEDLINE.
A mechanism-driven enantiodivergent approach to chiral 1,1′-bi-2-naphthols via catalytic asym. oxidative coupling of 2-naphthol derivatives is described for the first time. By utilizing 2-naphthol derivatives with low oxidation potential, the substrates were activated by either chiral mononuclear or dinuclear vanadium(V) catalyst to promote distinctively different asym. reaction pathways: single vs. dual substrate activation mechanisms.
Organic Letters published new progress about 21286-54-4. 21286-54-4 belongs to chlorides-buliding-blocks, auxiliary class Chiral,Chloride,Sulfonyl chlorides,Aliphatic cyclic hydrocarbon,Ketone, name is ((1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl)methanesulfonyl chloride, and the molecular formula is C10H15ClO3S, Quality Control of 21286-54-4.
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