Kiso, Yoshihisa published the artcileSilicon hydrides and nickel complexes. IV. Preparation of silicon-nickel complexes by the reaction of silicon hydrides with σ-alkyl-nickel complexes, Synthetic Route of 14799-93-0, the publication is Journal of Organometallic Chemistry (1974), 76(1), 95-103, database is CAplus.
Three silicon-nickel complexes, Ni(bipy)(SiX3)2 (I,X3 = Cl3; II, X3 = MeCl2, bipy = 2,2′-bipyridyl) and Ni(h1-C5H5 )-(PPh3)(SiCl3) (III, C5H5 = cyclopentadienyl), were prepared by treatment of silicon hydrides with appropriate alkyl-nickel complexes, Ni(bipy)R2 (IV, R = Me, V, R = Et) and Ni(h1-C5H5)(PPh3)Et (VI), resp. Both complexes I and III reacted with HCl or DCl to give the corresponding chlorosilane HSiX3 (or DSiX3) and Ni(bipy)Cl2, in good yields. II reacted with tetracyanoethylene to afford MeCl2SiSiCl2Me, but in low yield. III reacted with MeI to form MeSiCl3 (23.5% yield). The silicon-nickel complex I was inactive as catalyst for hydrosilylation of olefins, whereas the alkyl complexes V and VI were active.
Journal of Organometallic Chemistry published new progress about 14799-93-0. 14799-93-0 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(methyl)(octyl)silane, and the molecular formula is C9H20Cl2Si, Synthetic Route of 14799-93-0.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics