Lamaty, G. published the artcileAcid hydrolysis of 2-haloethylamines. I. Determination of kinetic conditions. Evaluation of the participant of the nitrogen lone pair in the loss of the halogen, Product Details of C5H13Cl2N, the publication is Bulletin de la Societe Chimique de France (1974), 2143-8, database is CAplus.
The kinetics of hydrolysis of haloamines, XCH2CH2NHR2+X- (I; R = H, Me, Et; X = Br, Cl) at 90 and 100° follow a first order rate law. Initial variations in linearity for the curve log [I] = kexp.(sec-1) are due to the competitive hydrolysis of I and its conjugate base. The rate of hydrolysis of the conjugate base is suppressed by the addition of small amounts of HClO4.
Bulletin de la Societe Chimique de France published new progress about 4584-49-0. 4584-49-0 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Salt,Amine,Aliphatic hydrocarbon chain, name is 2-Chloro-N,N-dimethylpropan-1-amine hydrochloride, and the molecular formula is C5H13Cl2N, Product Details of C5H13Cl2N.
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