Matsuda, Akira’s team published research in Chemical & Pharmaceutical Bulletin in 34 | CAS: 5034-06-0

Matsuda, Akira published the artcileNucleosides and nucleotides. LXVI. Synthesis of 8,6′-cyclo-6′-deoxyhexofuranosyladenines: adenosines fixed in an anti-conformation, SDS of cas: 5034-06-0, the publication is Chemical & Pharmaceutical Bulletin (1986), 34(4), 1573-8, database is CAplus.

For studies of the conformation of nucleosides around the glycosyl linkages, the carbon-bridged cycloadenosines I (R = OH, R¹ = H; R = H, R¹ = OH) were prepared by the following route. Treatment of N⁶-benzoyl-2′,3′-O-isopropylideneadenosine 5′-aldehyde with dimethyloxosulfonium methylide afforded the 5′,6′-anhydrohexofuranosyladenine II, which was treated with thiophenoxide to give the diastereomeric 6′-phenylthio derivatives III. Photoirradiation of III followed by 5′-O-acetylation afforded III. Attempted synthesis of a 8,7′-cycloheptofuranosyl derivative by way of photolysis of a 7′-phenylthioheptofuranosyladenine resulted in the formation of 5′,6′,7′-trideoxy-2′,3′-O-isopropylidene-β-D–ribo-heptofuranosyladenine. The nature of the CD spectra of I is discussed.

Chemical & Pharmaceutical Bulletin published new progress about 5034-06-0. 5034-06-0 belongs to chlorides-buliding-blocks, auxiliary class Salt,Aliphatic hydrocarbon chain, name is trimethyloxosulphonium chloride, and the molecular formula is C3H9ClOS, SDS of cas: 5034-06-0.

Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics