Mizuno, Noritaka published the artcileA Flexible Nonporous Heterogeneous Catalyst for Size-Selective Oxidation through a Bottom-Up Approach, HPLC of Formula: 23616-79-7, the publication is Angewandte Chemie, International Edition (2010), 49(51), 9972-9976, S9972/1-S9972/19, database is CAplus and MEDLINE.
The nonporous ([(Bu)4N]4[γ-SiW10O34(H2O)2]·H2O, 1.H2O) synthesized through a bottom-up approach sorbs EtOAc, which is highly mobile in the solid bulk of the compound, probably contributing to the easy co-sorption of olefins and H2O2. 1 Heterogeneously catalyzes size-selective oxidation (small olefins are much more preferentially epoxidized than large olefins) of various organic substances including olefins, sulfides, and silanes with aqueous H2O2 in EtOAc. 1 Can easily be separated by filtration and reused several times with retention of its high catalytic activity and is the 1st example for the heterogeneously catalyzed size-selective liquid-phase oxidation with H2O2 by a POM-based catalyst.
Angewandte Chemie, International Edition published new progress about 23616-79-7. 23616-79-7 belongs to chlorides-buliding-blocks, auxiliary class Phase Transfer Catalyst, name is N-Benzyl-N,N-dibutylbutan-1-aminium chloride, and the molecular formula is C19H34ClN, HPLC of Formula: 23616-79-7.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics