Ohmura, Toshimichi published the artcileCatalytic Functionalization of Methyl Group on Silicon: Iridium-Catalyzed C(sp3)-H Borylation of Methylchlorosilanes, Category: chlorides-buliding-blocks, the publication is Journal of the American Chemical Society (2012), 134(42), 17416-17419, database is CAplus and MEDLINE.
A Me group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80°, giving (borylmethyl)chlorosilanes selectively. For example, reaction of Me3SiCl with B2(pin)2 in the presence of [Ir(OMe)(COD)]2 and 3,4,7,8-Me4phen followed by addition of iPrOH gives iPrOSiMe2CH2B(pin) in 93% yield.
Journal of the American Chemical Society published new progress about 14799-94-1. 14799-94-1 belongs to chlorides-buliding-blocks, auxiliary class Aliphatic Chain, name is Dichloro(hexyl)(methyl)silane, and the molecular formula is C7H16Cl2Si, Category: chlorides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Chloride,
Chlorides – an overview | ScienceDirect Topics