Yoshihira, Kunitoshi published the artcileStereochemistry. XL. Rearrangement and trans-elimination contrary to the Chugaev reaction rule. 4. Thermal treatment on thionobenzoates, Application of 2-Chloro-N,N-dimethylpropan-1-amine hydrochloride, the publication is Yakugaku Zasshi (1969), 89(9), 1225-35, database is CAplus and MEDLINE.
Thermal treatment of xanthates bearing an anchimeric group causes rearrangement to dithiocarbonates or trans elimination depending on their conformation (contrary to the Chugaev reaction). Thiobenzoates, e.g. I, were similarly treated and the analogous conclusion was reached concerning results and mechanisms. The identification of 2-(dialkylamino)alkanethiols produced in this series was reexamined and Hansen’s report on the same problem was corrected with respect to isothiuronium salt formation and desulfurization by Raney Ni.
Yakugaku Zasshi published new progress about 4584-49-0. 4584-49-0 belongs to chlorides-buliding-blocks, auxiliary class Chloride,Salt,Amine,Aliphatic hydrocarbon chain, name is 2-Chloro-N,N-dimethylpropan-1-amine hydrochloride, and the molecular formula is C11H11BFNO4, Application of 2-Chloro-N,N-dimethylpropan-1-amine hydrochloride.
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