Friedel-Crafts Acylation of Chromium-Carbene-Complex-Derived Ketenes was written by Bueno, Ana B.;Moser, William H.;Hegedus, Louis S.. And the article was included in Journal of Organic Chemistry in 1998.Recommanded Product: 6834-42-0 This article mentions the following:
Photolysis of Cr alkoxycarbene complexes containing electron-rich aromatic systems on either the O or C group of the carbene C resulted in intramol. Friedel-Crafts acylation of the arene. For example, photolysis of (OC)5Cr:CMe(OCH2C6H4OMe-3) and 1 equivalent ZnCl2 in CH2Cl2/Et2O for 40 h gave 69% I. The carbene complexes were prepared from (OC)5Cr:CR(ONMe4) (R = Me, cyclopropyl, Ph) and R’OH (R’ = CH2C6H4OMe-3, CH2C6H4OH-3, CH2C6H3(OMe)2-3,4, CH2CH2C6H4OMe-3, CH2Ph, 2-furylmethyl) in the presence of pivaloyl chloride or acetyl bromide in CH2Cl2. In the experiment, the researchers used many compounds, for example, 2-(3-Methoxyphenyl)acetyl chloride (cas: 6834-42-0Recommanded Product: 6834-42-0).
2-(3-Methoxyphenyl)acetyl chloride (cas: 6834-42-0) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Recommanded Product: 6834-42-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics