Palladium-catalyzed salt-free double decarboxylative aryl allylation was written by Daley, Ryan A.;Topczewski, Joseph J.. And the article was included in Organic & Biomolecular Chemistry in 2019.SDS of cas: 225104-76-7 This article mentions the following:
This report describes a palladium-catalyzed decarboxylative aryl allylation between unactivated benzoic acids and allylic carbonates. This transformation successfully couples a variety of carbonates and benzoic acids in good yield (up to 94%) using 1 mol% palladium. This salt free allyl-arylation proceeds without added base, copper, or silver. The only stoichiometric byproducts are carbon dioxide and tert-butanol. In the experiment, the researchers used many compounds, for example, 3-Chloro-2,6-difluorobenzoic acid (cas: 225104-76-7SDS of cas: 225104-76-7).
3-Chloro-2,6-difluorobenzoic acid (cas: 225104-76-7) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.SDS of cas: 225104-76-7
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics