Ligand-ligand interactions and low frequency vibrations in chlorotetrakis(ethylene)iridium and bis(ethylene)chloroiridium dimer studied by inelastic neutron scattering and optical spectroscopy was written by Howard, Joseph;Waddington, Thomas C.. And the article was included in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics in 1978.Computed Properties of C8H16Cl2Ir2 This article mentions the following:
Incoherent inelastic neutron-scattering and Raman spectra were obtained for Ir(C2H4)4Cl (I) and [Ir(C2H4)2Cl]2 and a model was proposed for the interaction between the C2H4 ligands in I. The torsion of the axial C2H4 ligand was assigned at 45 cm-1 and the in-phase and out-of-phase torsions of the equatorial ligands assigned at 172 and 240 cm-1 resp. In the experiment, the researchers used many compounds, for example, Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1Computed Properties of C8H16Cl2Ir2).
Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Organochlorine compounds are lipophylic, meaning they are more soluble in fat than in water. This gives them a high tenancy to accumulate in the food chain (biomagnification).Computed Properties of C8H16Cl2Ir2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics