Ti-Mediated Efficient Reductive Dehalogenation of Carbon-Halogen Bonds was written by Gonzalez-Delgado, Jose A.;Prieto, Consuelo;Enriquez, Lourdes;Jaraiz, Martin;Lopez-Perez, Jose L.;Barrero, Alejandro F.;Arteaga, Jesus F.. And the article was included in Asian Journal of Organic Chemistry in 2016.Product Details of 3386-33-2 This article mentions the following:
A mild and efficient methodol. for the reductive dehalogenation of carbon-halogen bonds in both activated (allylic or benzylic) and non-activated halides with excess TiIII was thoroughly described. A detailed computational and exptl. study corroborates that the reaction occurred via the allyl(benzyl) radical and allyl(benzyl)-Ti, which was protonated by a Bronsted acid and proceeds regioselectively in the case of allylic derivatives This synthetic method was compatible with a wide range of functional groups and reaction conditions and thus presented a mild process for reductive dehalogenation in the field of organic synthesis. In the experiment, the researchers used many compounds, for example, 1-Chlorooctadecane (cas: 3386-33-2Product Details of 3386-33-2).
1-Chlorooctadecane (cas: 3386-33-2) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Product Details of 3386-33-2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics