Interlayered thin-film nanocomposite membrane with synergetic effect of COFs interlayer and GQDs incorporation for organic solvent nanofiltration was written by Li, Shuxuan;Yin, Yating;Liu, Shaoxiao;Li, Honghai;Su, Baowei;Han, Lihui;Gao, Xueli;Gao, Congjie. And the article was included in Journal of Membrane Science in 2022.Product Details of 4422-95-1 This article mentions the following:
The separation performance of current organic solvent nanofiltration (OSN) membranes are still not satisfied. In this work, an ultra-thin TpHz covalent organic frameworks (COFs) interlayer was in situ constructed in advance on polyimide substrate, then an ultra-thin polyamide separation layer incorporated with amino-functionalized graphene quantum dots (af-GQDs) was constructed via interfacial polymerization (IP). A high performance interlayered thin-film nanocomposite (iTFN) OSN membrane with integrally covalent bonding structure, ultra-thin and ultra-smooth surface was obtained after post crosslinking and activation. The effect of ultra-low concentrations for the polyamide reaction monomers, the COFs monomer Tp and the doped af-GQDs nanoparticle reveals that they could help to form a very thin (7-8 nm in thickness) and defect-free skin layer with very smooth surface (about 2.7 nm in roughness). The iTFN OSN membrane shows excellent solvent permeance and solute selectivity, with an ethanol permeance reaching 97.6 L m-2 h-1 MPa-1 and an RDB rejection higher than 99%. After a 180 h long-term filtration with 100 mg L-1 RB/DMF solution, it remained an RB rejection of higher than 99%, demonstrating its superior resistance to strong polar solvent. Our work paves a unique way for the fabrication of novel OSN membrane with both in situ constructed nanomaterials interlayer and nanomaterials incorporated in skin layer. In the experiment, the researchers used many compounds, for example, Trimesoylchloride (cas: 4422-95-1Product Details of 4422-95-1).
Trimesoylchloride (cas: 4422-95-1) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Product Details of 4422-95-1
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics