Cationic palladium and platinum complexes with diolefin ligands was written by Eaborn, Colin;Farrell, Nicholas;Pidcock, Alan. And the article was included in Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999) in 1976.COA of Formula: C10H10Cl2Pt This article mentions the following:
Cl-bridged complexes [M2L2Cl2][BF4]2 (M = Pt, Pd; L = cycloocta-1,5-diene, norborna-2,5-diene) were prepared from MLCl2 and [Et3O][BF4]. [Pd2L2Cl2][BF4]2 (L = cyclooctadiene) reacted with MeOH, AcOH, and H2O to give Pd2(2-RL1)2Cl2 (L1 = 5,6-η-cycloocta-5-enyl; R = MeO, AcO, HO), resp., but with PPh3, L was displaced to form [Pd2Cl2(PPh3)4][BF4]2. PPh3 reacted with the Pt analog to give [PtLCl(PPh3)][BF4]. [MLCl(PR3)]X [R3 = Ph3, Bu3, Me2Ph; X = SFO3, BF4, ClO4) were prepared from sym,trans-[M2Cl4(PR3)2], L, and SFO2(OMe)-C6H6, [Et3O][BF4]-CH2Cl2, and Na[ClO4]-Me2CO. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0COA of Formula: C10H10Cl2Pt).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.COA of Formula: C10H10Cl2Pt
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics