The study of the ultraviolet absorption of ortho-substituted anilines. II. N-Substituted ortho-halogenated anilines was written by Grammaticakis, P.. And the article was included in Bulletin de la Societe Chimique de France in 1949.Formula: C8H10ClN This article mentions the following:
The qual. relations between the spectra of the N-derivatives of o-toluidine and mesidine are generally retained when the Me group is replaced by Cl or Br. Br causes very slight, if any, shift toward the visible as compared with Cl. Spectra are reported of: o-ClC6H4NH2 (I); 2,4,6-Cl3C6H2NH2 (II); 2,4,6-Br3C6H2NH2 (III); the N-mono-Me and N,N-di-Me derivatives of I, II, and III; the N-Ac, N-Bz, and N-formyl derivatives of I, II, and III and their N-mono-Me derivatives; the N,N-di-Ac derivatives of II and III; the N-cyclohexylidene derivatives of I and II; the N-benzylidene derivatives of I, II, and III; the N-phenylcarbamyl derivatives of I, II, and III and their N-mono-Me derivatives; the N-PhSO2 derivative of I; the N-phenylcarbamyl derivative of mesidine and its mono-Bu derivative; the N-carbamyl derivatives of I and o-toluidine and o-acetotoluide. In the experiment, the researchers used many compounds, for example, 2-Chloro-N,N-dimethylaniline (cas: 698-01-1Formula: C8H10ClN).
2-Chloro-N,N-dimethylaniline (cas: 698-01-1) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Formula: C8H10ClN
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics