Sodium iodide as a novel, chemoselective and highly efficient catalyst for N-tert-butoxy carbonylation of amines at room temperature was written by Periyasamy, Senthil;Subbiah, Selvaraj. And the article was included in Journal of Chemical and Pharmaceutical Research in 2016.COA of Formula: C11H14ClNO2 This article mentions the following:
Com. available sodium iodide was found to be one of the best catalyst and practically an efficient protocol for the protection of various structurally and electronically divergent aryl and aliphatic amines using (BOC)2O at room temperature was presented. The reported method is chemoselective and the products isolated in high yields. In the experiment, the researchers used many compounds, for example, tert-Butyl (4-chlorophenyl)carbamate (cas: 18437-66-6COA of Formula: C11H14ClNO2).
tert-Butyl (4-chlorophenyl)carbamate (cas: 18437-66-6) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.COA of Formula: C11H14ClNO2
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics