Synthesis and properties of high-temperature mesomorphic polysiloxane (MEPSIL) solvents: biphenyl- and terphenyl-based nematic systems was written by Apfel, M. A.;Finkelmann, H.;Janini, G. M.;Laub, R. J.;Luehmann, B. H.;Price, A.;Roberts, W. L.;Shaw, T. J.;Smith, C. A.. And the article was included in Analytical Chemistry in 1985.Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:
Mesomorphic (liquid-crystalline) side-chain siloxanes were prepared for evaluation as stationary phases in gas chromatog. by hydrosilylation of 4-(allyloxy)benzoate esters by Me hydrogen siloxanes in the presence of a dicyclopentadienylplatinum (II)chloride [12083-92-0] catalyst. The products were characterized by IR, NMR, gas chromatog., DSC, elemental anal., and hot-stage, polarized optical microscopy. Their selectivity was substantially different from that of other common gas chromatog. solvents. The one best suited for use in gas chromatog. had m.p. 139°, nematic-isotropic transition temperature 319°, and practical operating limits of 150 to >300°. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Chlorinated organic compounds are found in nearly every class of biomolecules and natural products including alkaloids, terpenes, amino acids, flavonoids, steroids, and fatty acids. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Recommanded Product: Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics