Study on d0 Metal-Catalyzed Alkyl-Alkyl Cross-Coupling Enabled by a Redox-Active Ligand was written by Belli, Roman G.;Tafuri, Victoria C.;Joannou, Matthew V.;Roberts, Courtney C.. And the article was included in ACS Catalysis in 2022.SDS of cas: 76-83-5 This article mentions the following:
Herein, a redox-active ligand-enabled alkyl-alkyl cross-coupling using a d0 metal was described. This tris(amido) ScIII complex as well as the oxidized variant was thoroughly characterized (NMR, X-ray, EPR, CV, UV-vis, DFT). Insight into the likely radical nature of the mechanism is disclosed. Addnl., a substrate scope that includes functional groups incompatible with late-transition-metal catalysis and both coupling partners bearing 尾-hydrogens was reported. In the experiment, the researchers used many compounds, for example, (Chloromethanetriyl)tribenzene (cas: 76-83-5SDS of cas: 76-83-5).
(Chloromethanetriyl)tribenzene (cas: 76-83-5) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Aryl chlorides may be prepared by the Friedel-Crafts halogenation, using chlorine and a Lewis acid catalyst.SDS of cas: 76-83-5
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics