Preparation and ligand displacement reactions of diene(polyfluorophenyl)platinum(II) complexes was written by Deacon, G. B.;Nelson-Reed, K. T.. And the article was included in Journal of Organometallic Chemistry in 1987.HPLC of Formula: 12083-92-0 This article mentions the following:
The complexes PtR2(diene) [R = C6F5 or p-HC6F4; diene = cis,cis-cycloocta-1,5-diene (cod), dicyclopentadiene (dcy), norbornadiene (nbd), hexa-1,5-diene (hex)] have been prepared by the organolithium route. Reaction of PtCl2(cod) with an equimolar amount of TlO2CR (R = C6F5, p-HC6F4) in pyridine yields Pt(R)Cl(cod), which have been converted into Pt(R)X(cod) (X = Br or iodo) by halogen exchange reactions. Other decarboxylations result in diene displacement giving cis-Pt(C6F5)Cl(py)2 and cis– and trans-Pt(C6F5)2(py)2. The complexes, cis-Pt(C6F5)2L2 (L = py or Ph3P) and cis-Pt(p-HC6F4)2(PPh3)2 are formed by ligand replacement reactions of PtR2(cod), but Pt(C6F5)2 (cod) does not react with N,N,N‘,N‘-tetramethylethylenediamine (tmed) nor Pt(C6F5)2(nbd or dcy) with ethylenediamine (en). Diene displacement occurs more readily from PtR2(hex) giving Pt(C6F5)2L2 [L2 = cis-(NH3)2, en, tmed, 1,10-phenanthroline) and cis-Pt(p-HC6F4)2(PPh3)2. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0HPLC of Formula: 12083-92-0).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.HPLC of Formula: 12083-92-0
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics