Novel CpAg(I)-Containing Organometallic Coordination Polymers Generated from Fulvene Ligands was written by Dong, Yu-Bin;Jin, Guo-Xia;Zhao, Xia;Tang, Bo;Huang, Ru-Qi;Smith, Mark D.;Stitzer, K. E.;Zur Loye, Hans-Conrad. And the article was included in Organometallics in 2004.Reference of 1711-11-1 This article mentions the following:
Two new fulvene ligands, L1 and L2, have been synthesized by an aroylation reaction of the cyclopentadienyl anion. The coordination chem. of L1 and L2 was investigated. Two novel CpAg(I)-containing polymeric compounds, 1 ([Ag4(L1)2(渭-H2O)2(SO3CF3)4]路(渭-bis-畏1-C6H6))路H2O and 2 ([Ag2(L2)(H2O)(SO3CF3)2]路0.5(C6H6)), have been synthesized. Compounds 1 and 2 have been fully characterized by IR spectroscopy, elemental anal., and single-crystal x-ray diffraction. The solid state structure of 1 features a macro-ring-containing one-dimensional chain motif. The solid state structure of 2 features a one-dimensional double-chain motif. These double chains are further cross-linked to each other via CpAg(SO3CF3)2AgCp (Ag路路路Ag contact of 4.215(15) 脜) linkage into a novel 2-D network with large cavities (effective cross-section of ca. 21 脳 9 脜), in which the benzene guest mols. are located. In the experiment, the researchers used many compounds, for example, 3-Cyanobenzoyl chloride (cas: 1711-11-1Reference of 1711-11-1).
3-Cyanobenzoyl chloride (cas: 1711-11-1) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Aliphatic organochlorides are often alkylating agents as chlorine can act as a leaving group, which can result in cellular damage.Reference of 1711-11-1
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics