Kinetics of oxidation of 4-oxoacids by N-chlorosaccharin in aqueous acetic acid medium was written by Farook, N. A. Mohamed. And the article was included in Asian Journal of Chemistry in 2007.Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide This article mentions the following:
Kinetics of oxidation of substituted and unsubstituted 4-oxoacids (S) by N-chlorosaccharin (NCSA) in aqueous acetic acid medium were studied. The reaction follows first-order kinetics, each in 4-oxoacids, NCSA and H+. The effect of changes in the electronic nature of the substrate reveals that there is a development of pos. charge in the transition state. From the kinetic results and product anal., a suitable mechanism was proposed for the reaction of NCSA with 4-oxoacids. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organic chlorides can be used in production of: PVC, pesticides, chloromethane, teflon, insulators. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics