Homolytic displacement at carbon centers. XII. Regiospecific formation of N-allyl and N-cyclopropylcarbinyl sulfonamides and of allyl and cyclopropyl halides in the reaction of N-halo compounds with organocobaloximes was written by Johnson, Michael D.;Lampman, Gary M.;Koops, Roger W.;Das Gupta, B.. And the article was included in Journal of Organometallic Chemistry in 1987.Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide This article mentions the following:
Reaction of RCo(dmgH)2py [I, dmgH = dimethylglyoximato; R = R1CR2:CHCH2, H2C:CR1(CH2)2; R1 = H, Me; R2 = H, Me, Ph] with R3SO2NMeCl (II, R3 = Me, Ph) gave R4CR1R2CH:CH2 (III) and cyclopropanes IV (R4 = R3SO2NMe, Cl), resp., by attack of an N-centered radical on the terminal unsaturated carbon of I. Reaction of I [R = R1CH:CHCH2, H2C:CR1(CH2)2; R1 = H, Me] with AcNHBr, NBS, N-chlorosuccinimide, and N-chlorosaccharin gave III and IV (R4 = Br, Cl) by attack of a halogen-containing free radical on the terminal unsaturated carbon of I. Bromination of Me(CH2)5CH:CH2 with AcNHBr in the presence of 0.3 mol % I (R = MeCHEt) gave BrCH2CHBr(CH2)5Me in 92% yield after 1 h. In the experiment, the researchers used many compounds, for example, 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide).
2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide (cas: 14070-51-0) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. Alkyl chlorides are versatile building blocks in organic chemistry. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available.Quality Control of 2-Chlorobenzo[d]isothiazol-3(2H)-one 1,1-dioxide
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics