Reactions of perfluoroalkanesulfonyl chlorides with silyl enol ethers catalyzed by a ruthenium(II) phosphine complex was written by Kamigata, Nobumasa;Udodaira, Kumiko;Shimizu, Toshio. And the article was included in Phosphorus, Sulfur and Silicon and the Related Elements in 1997.Product Details of 7476-66-6 This article mentions the following:
Reactions of trifluoromethane- and tridecafluorohexanesulfonyl chlorides with silyl enol ethers have been investigated in the presence of a ruthenium(II) phosphine complex. Perfluoroalkylation and chlorination occurred depending on the substituent on the silyl enol ether, i.e., perfluoroalkylated compound was selectively obtained in the reactions with silyl enol ether possessing an electron-withdrawing group while chlorinated compounds were selectively formed in the reaction with a silyl enol ether possessing an electron-donating group. In the experiment, the researchers used many compounds, for example, Methyl 2-chloro-2-phenylacetate (cas: 7476-66-6Product Details of 7476-66-6).
Methyl 2-chloro-2-phenylacetate (cas: 7476-66-6) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen.While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Product Details of 7476-66-6
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics