Nucleophilic Attack of Carbonyl-Stabilized Phosphorus Ylides on Neutral and Cationic Alkene Platinum(II) Complexes was written by Vicente, Jose;Chicote, Maria Teresa;MacBeath, Calum;Jones, Peter G.. And the article was included in Organometallics in 2003.Application In Synthesis of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) This article mentions the following:
The carbonyl-stabilized phosphorus ylides Ph3P:CHCO2R (R = Me, Et) react with the platinum complexes [PtCl(畏2-CH2:CH2)(N,N,N’,N’-tetramethylethylenediamine)]ClO4 and [PtCl2(畏4-diene)] (diene = 1,5-hexadiene (C6H10), dicyclopentadiene (C10H12), 4-vinylcyclohex-1-ene (C8H12), norbornadiene (C7H8)) to give complexes resulting from nucleophilic attack of the ylide at one of the olefinic carbons. The crystal structures of [PtCl2{畏3-C6H10CH(PPh3)CO2Et}], [PtCl2{畏3-C10H12CH(PPh3)CO2Me}]路0.5CH2Cl2, and [PtCl2{畏3-C8H12CH(PPh3)CO2Me}]路2CHCl3 are reported and indicate an exo attack in the case of the dicyclopentadiene complex and anti-Markovnikov addition (attack at the CH2 group) in the other two complexes. In the experiment, the researchers used many compounds, for example, Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0Application In Synthesis of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)).
Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II) (cas: 12083-92-0) belongs to organic chlorides. An organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Application In Synthesis of Dichlorodi(cyclopenta-1,3-dien-1-yl)platinate(II)
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Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics