Synthesis, Structure, and Reactivity of Iridium(III) Complexes Containing a 4,6-Dimethyl-1,3-benzenediphenylimine Pincer Ligand was written by Wingard, Leah A.;Finniss, Mathew C.;Norris, Michael;White, Peter S.;Brookhart, Maurice;Templeton, Joseph L.. And the article was included in Inorganic Chemistry in 2013.Recommanded Product: Chlorobis(ethylene)iridium(I) dimer This article mentions the following:
A nonheterocyclic bis(imino)aryl ligand with blocking Me substituents, 4,6-dimethyl-1,3-benzenediphenylimine (NCHN), has been synthesized. Metalation via oxidative addition proceeds under mild conditions with the Ir(I) reagent [Ir(CH2=CH2)2(Cl)]2 to produce the Ir(III) product (NCN)Ir(CH2CH3)(Cl). Neutral nucleophiles such as water or triphenylphosphine add readily to the vacant sixth coordination site. Protonation of the Et group results in loss of ethane and formation of a dicationic chloride-bridged (NCN)Ir dimer. Alternatively, the chloride ligand can be abstracted from (NCN)Ir(CH2CH3)(Cl) to provide access to various neutral and cationic species, including (NCN)Ir(CH2CH3)(OAc) (OAc = acetate), [(NCN)Ir(CH2CH3)(bpy)][BF4] (bpy = 4,4′-bipyridine), [(NCN)Ir(CH2CH3)(NCCH3)2][BF4], and [(NCN)Ir(CH2CH3)(OH2)2][BF4], which is water soluble In the experiment, the researchers used many compounds, for example, Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1Recommanded Product: Chlorobis(ethylene)iridium(I) dimer).
Chlorobis(ethylene)iridium(I) dimer (cas: 39722-81-1) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. While alkyl bromides and iodides are more reactive, alkyl chlorides tend to be less expensive and more readily available. Alkyl chlorides readily undergo attack by nucleophiles.Recommanded Product: Chlorobis(ethylene)iridium(I) dimer
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics