Bellotti, Peter; Koy, Maximilian; Gutheil, Christian; Heuvel, Steffen; Glorius, Frank published the artcile< Three-component three-bond forming cascade via palladium photoredox catalysis>, Quality Control of 22952-32-5, the main research area is carbocycle heterocycle preparation; bromide diene nucleophile bond forming cascade palladium photoredox catalysis.
A highly modular radical cascade strategy based upon radical cyclization/allylic substitution sequence between alkyl/aryl bromides, 1,3-dienes and nucleophiles ranging from sulfinates to amines, phenols and 1,3-dicarbonyls was described. Palladium phosphine complexes – which merge properties of photo- and cross coupling-catalysts – allowed to forge three bonds with complete 1,4-selectivity and stereocontrol, delivering highly value added carbocyclic and heterocyclic motifs that could feature – inter alia – vicinal quaternary centers, free protic groups, gem-difluoro motifs and strained rings. Furthermore, a flow chem. approach was for the first time applied in palladium-photocatalyzed endeavors involving radicals.
Chemical Science published new progress about 1,3-Alkadienes Role: RCT (Reactant), RACT (Reactant or Reagent). 22952-32-5 belongs to class chlorides-buliding-blocks, and the molecular formula is C7H6Cl2O3S, Quality Control of 22952-32-5.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics