Amani, Javad; Molander, Gary A. published the artcile< Toward Efficient Nucleophilic Azaborine Building Blocks for the Synthesis of B-N Naphthyl (Hetero)arylmethane Isosteres>, Name: 1-Chloro-3,5-difluorobenzene, the main research area is aryl chloride coupling fluoroboratomethylborazaronaphthalene preparation arylmethylborazaronaphthalene arylmethylbenzazaborine.
To develop a method for the synthesis of a class of azaborines, K 2-(trifluoroboratomethyl)-2,1-borazaronaphthalenes were synthesized to serve as nucleophilic building blocks. In Pd-catalyzed cross-coupling reactions with (hetero)aryl chlorides they serve to produce a variety of pseudobenzylic (hetero)aryl substituted azaborines. K 2-(trifluoroboratomethyl)-2,1-borazaronaphthalenes are crystalline solids that are more stable than 2-(chloromethyl)-2,1-borazaronaphthalenes and have a broader substrate scope in cross-coupling reactions compared to their pseudobenzylic chloride counterparts.
Organic Letters published new progress about Aryl chlorides Role: RCT (Reactant), RACT (Reactant or Reagent). 1435-43-4 belongs to class chlorides-buliding-blocks, and the molecular formula is C6H3ClF2, Name: 1-Chloro-3,5-difluorobenzene.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics