In 2022,Sakamoto, Ryota; Odagi, Minami; Izumiseki, Atsuto; Konuki, Kaname; Nagasawa, Kazuo published an article in Journal of Organic Chemistry. The title of the article was 《Stereodivergent Synthesis of 1,3-Dienes via Protodeboronation of Homoallenylboronic Esters》.Recommanded Product: 5781-53-3 The author mentioned the following in the article:
A versatile synthesis of homoallenylboronic esters via lithiation-borylation and subsequent 1,2-rearrangement was reported. The resulting homoallenylboronic esters were successfully converted into Z- and E-1,3-dienes by protodeboronation using Bu4NF and B(C6F5)3/PhOH, resp. In the experiment, the researchers used Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3Recommanded Product: 5781-53-3)
Methyl 2-chloro-2-oxoacetate(cas: 5781-53-3) belongs to acyl chlorides. In the laboratory, acyl chlorides are generally prepared by treating carboxylic acids with thionyl chloride (SOCl2). The reaction is catalyzed by dimethylformamide and other additives.Recommanded Product: 5781-53-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics