On September 3, 2021, Pollack, Scott R.; Dion, Amelie published an article.HPLC of Formula: 14602-86-9 The title of the article was Metal-free stereoselective synthesis of (E)- and (Z)-N-monosubstituted β-aminoacrylates via condensation reactions of carbamates. And the article contained the following:
Two efficient, stereoselective methods for the preparation of (E)- or (Z)-β-aminoacrylates via acid- or base-promoted condensation reactions of carbamates are described. The base-promoted reaction is E-selective, while acid catalysis can, through the choice of solvent, selectively form E or Z. The acid-catalyzed E-selective process proceeds through a crystallization obviating the need for chromatog. purification The experimental process involved the reaction of (1R,2S,5R)-2-Isopropyl-5-methylcyclohexyl carbonochloridate(cas: 14602-86-9).HPLC of Formula: 14602-86-9
The Article related to carbamate alkoxyacrylate acid catalyst metal free diastereoselective condensation reaction, dialkoxypropanoate carbamate acid catalyst metal free diastereoselective condensation reaction, propynoate carbamate base catalyst diastereoselective condensation reaction, aminoacrylate preparation stereoselective metal free and other aspects.HPLC of Formula: 14602-86-9
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics