The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Synthetic Route of 12112-67-3.
Li, Feng;Thiele, Sophia;Klok, Harm-Anton research published 《 Polymethylene Brushes via Surface-Initiated C1 Polyhomologation》, the research content is summarized as follows. Surface-initiated polymerization reactions are a powerful tool to generate chain-end-tethered polymer brushes. This report presents a synthetic strategy that gives access to structurally well-defined hydrocarbon polymer brushes of controlled mol. weights, which can be further modified to generate more complex surface-attached polymer architectures. The hydrocarbon brushes reported in this study are polymethylene brushes that are obtained via surface-initiated C1 polyhomologation of dimethylsulfoxonium methylide. The strategy outlined here is based on the use of an alkylboronic acid pinacol ester initiator, which allows for controlled, unidirectional chain growth by monomer insertion into only the C-B bond of the initiator and which presents the polymerization active group at the growing polymer chain end. This surface-initiated C1 polyhomologation methodol. is compatible with photopatterning strategies and can be used to generate micropatterned polymethylene brush films. Furthermore, conversion of the boronic ester chain-end functionalities to hydroxyl groups allows for selective chain-end modification and enables access to a variety of surface-anchored block copolymer architectures by chain extension via, for example, ring-opening or atom transfer radical polymerization chemistries.
12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Synthetic Route of 12112-67-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics