Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer.
Rivas, Christopher E.;Alvarado-Monzon, Jose C.;Gonzalez-Garcia, Gerardo;Jimenez-Halla, J. Oscar C.;Rangel-Garcia, Jesus;Cristobal, Crispin;Lopez, Jorge A. research published 《 Oxidative Coordination versus C3-C(O)Me Bond Cleavage in Acetylacetonate Iridium Complexes》, the research content is summarized as follows. Iridabicycles [Ir{κ3-N,C,O-(pyC(H):C(C(O)Me))2}(Cl)(L-L)](L-L=cod (cod=1,5-cyclooctadiene), 1a; bipy (bipy=2,2′-bipyridine), 1b) have been obtained by oxidative coordination of 3-(pyridine-2-yl-methylene)pentane-2,4-dione L1, to the complexes [{Ir(μ-Cl)(cod)}2] and [{Ir(μ-Cl)(coe)2}2] (coe=cis-cyclooctene), the latter in the presence of bipy. Remarkably, cleavage of the C3-C(O)Me bond of L1 has instead been achieved in the reaction with [Ir(Cl)(dmb)2] (dmb=2,3-dimethylbutadiene), yielding a compound formulated as [Ir{κ2-N,C-(pyC(H)C(C(O)Me))}(CO)(μ-Cl)(Me)]2, 2. Treatment of dimer 2 with DMSO or PMe3 produced the complexes[Ir{κ2-N,C-(pyC(H)C(C(O)Me))}(CO)Cl(Me)L] (L=DMSO, 3a; PMe3, 3b). Plausible mechanisms for the reactions leading to complexes 1 and 2 are proposed by means of DFT calculations
Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, 12112-67-3.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics