Electrocatalytic activation of organic chlorides via direct and indirect electron transfer using atomic vacancy control of palladium-based catalyst was written by Qin, Shiyi;Lei, Chao;Wang, Xuxu;Chen, Wenqian;Huang, Binbin. And the article was included in Cell Reports Physical Science in 2022.Related Products of 13820-53-6 The following contents are mentioned in the article:
Electrocatalytic dehalogenation (EDH) is a promising green technol. for the breakage of strong carbon-chlorine (C-Cl) bonds that have fundamental importance in organic chem. and environmental remediation. The lack of fundamental understanding and practical issues such as potential secondary pollution, side reactions (e.g., hydrogen-evolution reaction), deficiency in catalytic activity, and/or stability have limited the adoption of EDH technol. Here, we address these problems by designing a palladium-based nanocatalyst with precise control of at. vacancies to exploit the combination of direct and indirect EDH. Exptl. and theor. investigations show that at. vacancies can promote electron transfer on the catalyst surface to enhance the generation/storage capacity of at. hydrogen and to simultaneously facilitate dissociative electron transfer to C-Cl bond. Our work guides the design of at.-vacancy-rich palladium-based electrocatalysts and provides a new strategy for efficient electro-dehalogenation in water and fundamental insights into the relationship of different dehalogenation mechanisms for accurate quant. prediction. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Related Products of 13820-53-6).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organochlorines are organic compounds having multiple chlorine atoms. They were the first synthetic pesticides that were used in agriculture. They are resistant to most microbial and chemical degradations. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Related Products of 13820-53-6
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics