Au decorated Pd nanowires for methane oxidation to liquid C1 products was written by Xu, Yueshan;Wu, Daoxiong;Deng, Peilin;Li, Jing;Luo, Junming;Chen, Qi;Huang, Wei;Shim, Chong Michael;Jia, Chunman;Liu, Zhongxin;Shen, Yijun;Tian, Xinlong. And the article was included in Applied Catalysis, B: Environmental in 2022.Safety of Sodium tetrachloropalladate(II) The following contents are mentioned in the article:
The direct methane (CH4) oxidation to high value-added C1 chems. is a great promising strategy to explore the CH4 resource utilization. However, the low activity and selectivity of catalytic performance remains a great conundrum due to the difficulty to activate the C-H bond and the unmanageable over oxidation Herein, PdxAuy nanowires (NWs) with various Pd/Au at. ratios are presented as ideal models to explore the at.-level effect of PdAu atoms for the direct CH4 oxidation The influence of reaction parameters are systematically investigated, and Pd9Au1 NWs display a maximum yield of 2890.3μmol g-1 h-1 with 99% selectivity for the liquid C1 oxygenated products. This enhanced performance is attributed to the combination of one-dimensional structure and the synergistic effect from the suitable portion of Au on Pd sites, which regulates bond strength between adsorbed radicals (•OH, •OOH, •CH3) and PdAu atoms, confirmed by the d. function theory calculations This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Safety of Sodium tetrachloropalladate(II)).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Safety of Sodium tetrachloropalladate(II)
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics