Electrochemistry of Ferrocene-Functionalized Phosphonium Ionic Liquids was written by Weaver, Joshua E. F.;Breadner, Daniel;Deng, Fanguo;Ramjee, Bala;Ragogna, Paul J.;Murray, Royce W.. And the article was included in Journal of Physical Chemistry C in 2011.Synthetic Route of C6H12BrCl The following contents are mentioned in the article:
The synthesis of and voltammetry in undiluted form of several ferrocene-functionalized phosphonium ionic liquids is reported. Electron transport in the mixed valent diffusion layer around an electrode occurs primarily by Fc+/0 electron self-exchange reactions, as opposed to phys. diffusion of the ferrocenated phosphonium species. The apparent diffusion coefficients for electron transport and for the counterions of the ionic liquid, and in particular their activation energy barriers, are similar to one another, evidence for the control of rates of electron transport by relaxation of the counterion atm. For a net transport of electronic charge to accompany electron transfer, counterion displacement must occur to relax the charge displacement associated with the electron transfer. The ferrocenated phosphonium ionic liquids thus behave in a manner like that of previously studied redox ionic liquids based on combinations of redox groupings with imidazolium and with short-chain polyether functionalities. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Synthetic Route of C6H12BrCl).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organochlorines stimulate the central nervous system and cause convulsions, tremor, nausea, and mental confusion. Examples are dichlorodiphenyltrichloroethane (DDT), chlordane, lindane, endosulfan, and dieldrin. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Synthetic Route of C6H12BrCl
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics