Nitrogen doped carbon-distributed and nitrogen-stabilized ultrafine FeM (M = Pd, Pt, Au) nanoclusters for doxorubicin detoxification was written by Fu, Haoyang;Li, Meirong;Xu, Qianyu;Chen, Guoliang;Zou, Yunjie;Zhang, Weixian;Li, Shuzhou;Ling, Lan. And the article was included in Applied Catalysis, B: Environmental in 2022.Electric Literature of Cl4Na2Pd The following contents are mentioned in the article:
Downsizing supported metal of Fe0-based materials in dealing with ever-growing pharmaceutical contamination issues are highly desired but still challenging. Herein, we develop a modular design protocol to synthesize a family of ultrafine alloy nanoclusters embedded in a nitrogen-enriched carbon framework (NEC@FeM (M=Pd, Pt, Au)). Engineering the fine structure of nitrogen-enriched carbon and interfacial interaction with bimetallic nanoclusters largely suppresses bimetallic overgrowth, eventually producing supported ultrafine (< 4 nm), highly dispersed, well-alloyed nanoclusters. The alloying Fe0 with M for ultrafine nanoclusters optimize the electron flow, chem. stability, and catalytic property, resulting in the obtained NEC@FeM exhibiting excellent doxorubicin (DOX) degradation performance. D. functional theory calculation combined with exptl. results attribute the outstanding DOX degradation ability of NEC@FePd originally to the synergistic effect of enhanced DOX affinity and efficient electrons transfer from Fe to DOX. This work provides a paradigm for the design of ultrafine Fe0-based nanocluster with application in pollution control. This study involved multiple reactions and reactants, such as Sodium tetrachloropalladate(II) (cas: 13820-53-6Electric Literature of Cl4Na2Pd).
Sodium tetrachloropalladate(II) (cas: 13820-53-6) belongs to organic chlorides. Organic chlorides are compounds containing a carbon-chlorine bond, which are widely used in the oil field as a wax dissolver. Alkanes and aryl alkanes may be chlorinated under free radical conditions, with UV light. However, the extent of chlorination is difficult to control.Electric Literature of Cl4Na2Pd
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics