Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides was written by Fang, Yi;Rogge, Torben;Ackermann, Lutz;Wang, Shun-Yi;Ji, Shun-Jun. And the article was included in Nature Communications in 2018.Reference of 6294-17-3 The following contents are mentioned in the article:
Herein, a user-friendly, nickel-catalyzed reductive thiolation of unactivated primary and secondary alkyl bromides with thiosulfonates as reliable thiolation reagents, which are easily prepared and bench-stable is presented. Furthermore, a series of selenides is also prepared in a similar fashion with selenosulfonates as selenolation reagents. This catalytic method offers a facile synthesis of a wide range of unsym. alkyl-aryl or alkyl-alkyl sulfides and selenides I (R = -CH2Ph, -OPh, -CH2CH2CN, etc.; X = S, Se; R1 = Ph, 4-MeC6H4, 4-MeOC6H4, etc.) under mild conditions with an excellent tolerance of functional groups. Likewise, the use of sensitive and stoichiometric organometallic reagents can be avoided. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Reference of 6294-17-3).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. The hydrocarbon processing industry (HPI) and others are affected by damage caused by these substances. The haloform reaction, using chlorine and sodium hydroxide, is also able to generate alkyl halides from methyl ketones, and related compounds. Chloroform was formerly produced thus.Reference of 6294-17-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics