Synthesis of Enamides by Ruthenium-Catalyzed Reaction of Alkyl Azides with Acid Anhydrides in Ionic Liquid was written by Pak, Han Kyu;Han, Junghoon;Jeon, Mina;Kim, Yongjin;Kwon, Yearang;Park, Jin Yong;Rhee, Young Ho;Park, Jaiwook. And the article was included in ChemCatChem in 2015.Related Products of 6294-17-3 The following contents are mentioned in the article:
Enamides were synthesized by a ruthenium-catalyzed one-pot, one-step procedure from alkyl azides and acid anhydrides. The substrate scope includes not only secondary azides, but also primary aliphatic ones to give a wide range of enamides containing various functional groups. This one-step procedure was based on the newly discovered activity of Severin’s diruthenium complex ([CpR̂uCl2]2: Cp=̂η5-1-methoxy-2,4-di-tert-butyl-3-neopentylcyclopentadienyl) for the transformation of alkyl azides into the corresponding N-H imine intermediates in ionic liquids The formation of ruthenium tetrazene complexes was observed in the stoichiometric reaction of Severin’s complex with alkyl azides, which acted as the catalyst for the formation of N-H imine intermediates. This study involved multiple reactions and reactants, such as 1-Bromo-6-chlorohexane (cas: 6294-17-3Related Products of 6294-17-3).
1-Bromo-6-chlorohexane (cas: 6294-17-3) belongs to organic chlorides. Chlorination modifies the physical properties of hydrocarbons in several ways. These compounds are typically denser than water due to the higher atomic weight of chlorine versus hydrogen. Alkyl chlorides readily react with amines to give substituted amines. Alkyl chlorides are substituted by softer halides such as the iodide in the Finkelstein reaction.Related Products of 6294-17-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics